Synthesis of digermylene-stabilized linear tetraboronate and boroxine.
نویسندگان
چکیده
Two newly discovered linear compounds tetraboronate and boroxine stabilized by digermylene are reported, which feature a B4O5 chain and a B3O3 ring, respectively. DFT calculations reveal that not only can digermylene stabilize the electron-deficient boron centers, but also increase the energies of the LUMOs of the boron moiety. Our results provide a hint for the development of boronate covalent organic frameworks.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 8 شماره
صفحات -
تاریخ انتشار 2016